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Are there risks to transporting carbon dioxide in pipelines?

CO2 pipeline accidents have been rare, but as with pipelines carrying oil, natural gas, or hazardous chemicals, if ruptures are allowed to happen they can be very serious.

 

July 10, 2024

The United States is currently home to about 5,000 miles of pipelines that carry carbon dioxide around the country (compared to about 3 million miles of pipeline for natural gas).1 Today, CO2 is mostly transported for oil and gas drilling: companies pump CO2 underground to loosen more fossil fuels from the ground, a tool called “enhanced oil recovery.” But if many more CO2 pipelines are built in the future, it will likely be because they can help address climate change. CO2 is a climate-warming greenhouse gas, and through a technology called carbon capture and storage, it can be collected from smokestacks or removed from the air itself. We can then transport this CO2 through pipelines to storage locations, and bury it underground where it won’t warm the planet.

Are these CO2 pipelines safe? “​​Nothing is risk-free. But we have lots and lots of pipelines criss-crossing the United States,” says Howard Herzog, a Senior Research Engineer at the MIT Energy Initiative. “Compared to at least the materials in those pipelines, transporting CO2 is relatively safe.” The U.S. maintains about 75,000 miles of pipelines that carry other hazardous liquids, including toxic or flammable ones like ammonia and propane, and more than 84,000 carrying crude oil.2

Researchers have found that the failure rates for CO2 pipelines are similar to those for pipelines carrying oil and gas—which is to say, failures are relatively rare, but are worth taking serious precautions to prevent. From 1986 to 2021, the U.S. recorded around three accidents related to onshore CO2 pipelines per year.3 (Although it’s important to remember that our small network of CO2 pipelines means we have limited safety data.) And while big ruptures could release large amounts of CO2, which would be both dangerous to people and a problem for the climate, the data shows smaller leaks have been much more common. From 1994 to 2021, leaks accounted for 48 percent of CO2 pipeline incidents while ruptures accounted for 3 percent.3

Serious ruptures can happen, though—for instance, if a natural disaster, like an earthquake or flood, disrupts the integrity of a pipeline. This is what happened in the only mass-exposure event from a CO2 pipeline failure to date, when a landslide damaged an underground pipeline carrying CO2 near the village of Satartia, Mississippi, in 2020.

If a pipeline is compromised, CO2 can leak from it. CO2 is transported at high pressures in a “supercritical” liquid phase, but in the open air, it turns to gas as it rushes out of a ruptured pipe. Dry ice—the solid form of CO2—may also form at the opening, which could further damage the pipeline.

As a gas, carbon dioxide is heavier than air. When large amounts of it are released, it hugs the ground and can displace oxygen—including in people's lungs. “The biggest risk is it being an asphyxiant,” says Herzog. Whether that happens depends on the amount of CO2 that escapes, the landscape of the region, and the weather. In addition to asphyxiation, breathing in concentrated CO2 can cause headaches, dizziness, sweating, increased heart rate, and other maladies. If people can get to fresh air, these symptoms typically pass (although treatment with oxygen is recommended)—but if high levels of CO2 sit in low-lying areas on a windless day, or build up indoors, people could be hurt or killed. After the rupture in Satartia, forty-five people went to the hospital for treatment.

If other substances are mixed with the CO2, that can also present dangers. The rupture that impacted Satartia, for instance, also released hydrogen sulfide, a toxic chemical that can cause convulsions, coma, and even death. “I think with high probability it was the hydrogen sulfide that sent people to the hospital,” says Herzog. “Patients reported a green gas and rotten egg smell, which could only be hydrogen sulfide, and this is a highly toxic chemical. Fortunately, CO2 pipelines carrying toxic materials are the exception, not the rule. As CO2 pipelines get built for carbon capture and storage, as opposed to enhanced oil recovery, there will be no reason to transport toxic chemicals in them.”

In April 2024, another section of CO2 pipeline in Mississippi, owned by the same company as the Satartia pipe, also failed, though the cause is still being investigated.

Building CO2 pipelines far from people, and ensuring emergency procedures are in place, can reduce risks if ruptures do happen. Prior to the rupture in Satartia, there had been one injury associated with carbon pipelines in the U.S. in the last two decades.4

Regulations and careful management can also help make pipelines as safe as possible, says Herzog. Operators must “dry” CO2 and monitor it for impurities, including even water, before it enters a pipeline, so that reactions in the pipe don’t produce acids that may cause corrosion.5 Checking valves and fittings regularly should let companies know whether equipment is damaged or leaking. And regulators have a responsibility to make sure companies follow these practices, monitor for leaks, and accurately report them. (Research has shown oil and gas pipeline leaks across the U.S. have gone undetected in the past.6)

As carbon capture becomes more common, companies are expected to build out many more pipelines—up to 66,000 miles of them by 20507—to ferry CO2 around the country. To avoid future failures, the U.S. Department of Transportation’s Pipeline and Hazardous Materials Safety Administration recently began the process to create new rules for CO2 pipelines and emergency preparedness.8 Those regulations will be important, because many scientists agree we will need to remove some carbon from the atmosphere to meet the world’s climate targets and minimize the harms of climate change. The transport of carbon for underground storage will need to be safe and effective at scale if we expect to include carbon removal in our toolkit of climate solutions.

 

Thank you to Hans of Sydney, Australia, for the question.

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Footnotes

1 "Natural Gas Explained." Energy Information Administration, March 2024.

2 "Annual Report Mileage for Hazardous Liquid or Carbon Dioxide Systems." U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, July 2024.

3 Vitali, Matteo et. al, "Statistical analysis of incidents on onshore CO2 pipelines based on PHMSA database." Journal of Loss Prevention in the Process Industries, Volume 77, July 2022, doi:10.1016/j.jlp.2022.104799

4 Parfomak, Paul W., "Carbon Dioxide Pipelines: Safety Issues." Congressional Research Service, June 2022.

5 Hoa, Le Quynh et. al, "On the Corrosion Mechanism of CO2 Transport Pipeline Steel Caused by Condensate: Synergistic Effects of NO2 and SO2." National Library of Medicine, Volume 12, Issue 3, February 2019, doi:10.3390/ma12030364

6 Sherwin, Evan D. et. al, "US oil and gas system emissions from nearly one million aerial site measurements." Nature, Volume 627, March 2024, doi:10.1038/s41586-024-07117-5.

7 Larson, Eric et. al, "Net-Zero America: Potential Pathways, Infrastructure, and Impacts." Andlinger Center for energy + the environment, Princeton University, October 2021.

8 "Pipeline Safety: Safety of Carbon Dioxide and Hazardous Liquid Pipelines," Office of Information and Regulatory Affairs, 2023.

Want to Learn More?

Listen to this episode of MIT's "Today I Learned: Climate" podcast on storing CO2 underground.

Transcriptions

LHF: Hello, and welcome to Today I Learned: Climate, MIT’s climate change podcast. I’m Laur Hesse Fisher. And today, we’re talking about storing carbon dioxide underground. Which is something companies are doing right now, today, to the tune of tens of millions of tons a year.

Why? Well, if we put CO2 into the atmosphere—say, by burning coal, oil and gas—it heats up our planet. So people have come up with ways to capture this CO2 from the smokestacks and exhaust streams of coal, gas and industrial plants, so that it can’t escape into the atmosphere. There is even technology that can pull CO2 out of the air around us, something that folks call “direct air capture”. Whether pulling it from a smokestack or from the air, companies compress that CO2 into a fluid, pump it underground, and voila! It can’t contribute to climate change. 

If you’re interested in how these technologies work – and its benefits and challenges –  you can check out our two episodes: TIL about carbon capture, and TIL about removing CO2 from the atmosphere.

But now you might be wondering—what happens to this liquified CO2 under our feet? Is it dangerous? You might ask us, as Barbara Ann W. of North Carolina did: could pumping CO2 underground cause earthquakes or contaminate drinking water? Or you might, like Christopher B. of the United Kingdom, ask us: is there a risk that CO2 stored underground will escape?

Today, we’re answering these questions with help from Prof. Brad Hager. He’s a geophysicist and Associate Director of MIT’s Earth Resources Laboratory.

BH: We actually have a lot of experience with fluids under pressure underground. I mean, oil and natural gas themselves are trapped in the subsurface for millions of years, until someone comes along and drills a hole and lets them out. So because of the oil and gas industry, we know a lot about conditions under which fluids are trapped stably underground.

LHF: One way to think about carbon storage is that it’s returning carbon to where we got it. The carbon was part of oil and gas snug below the earth, we drilled it out and burned it to make energy, and now we’re collecting it and pumping it down there again as liquid CO2.

Still, you can’t just drill a hole anywhere you like and start pumping CO2 into it. That really could cause leaks and earthquakes.

BH: The big thing which determines whether injecting fluids causes earthquakes is basically the geology that you're injecting into. You do not want to inject into an area that has active faults. And you don't want to inject into an area that has brittle rocks.

LHF: If you inject any kind of fluid underground, it’s going to raise the pressure in the surrounding rocks. And if you’re injecting near a fault line, which are areas more susceptible to earthquakes, that pressure might actually slide the earth on top of it around. It’s kind of like turning on an air hockey table: you add some pressure coming up from below, which moves around the puck.

BH: If the local rocks are brittle, like, say, sandstone or granite, they’re also more likely to crack. And just like injecting near a fault line, that could trigger an earthquake, and it could let the carbon dioxide leak back out.

LHF: That hasn’t been documented at any CO2 storage sites, but wastewater has leaked when oil and gas companies pump this wastewater underground, so we know it’s a real risk.

What you want, ideally, is some sort of underground formation that has room to take in a bunch of fluid without moving or cracking.

Rocks like sandstone and limestone are porous. If you inject CO2 into these, it can seep into the pores of these stones and stay there, kinda like water seeping into sand. But you don’t want the whole formation to be porous.

BH: You also want a “caprock”: a hard layer on top that seals in the CO2. The caprock should be solid, but a little malleable. Shale is often a good candidate.

And finally, you want to inject the CO2 quite deep, at least 3,000 feet. That will keep it at a high pressure, so it remains a dense fluid and doesn’t turn back into a gas. It’s also deeper than the aquifers that we use for drinking water.

LHF: Put it all together, and that’s an awfully specific list of requirements. You might be wondering: how do we even find these places?

BH: It requires a lot of study. But with fairly standard techniques that the oil and gas industry uses all the time. You’d start with seismic reflection studies to characterize the structures.

LHF: That means that geologists make a vibration at the Earth’s surface, using something like an air gun or a piston that hits the ground really fast. That creates a seismic wave that travels underground and then reflects back up, and with special equipment we can “listen” for what kinds of rocks are underground.

BH: And if that looks promising you’d drill some test holes to get some ground truth on those seismic images, so you can actually sample the rocks that are there and understand things like their porosity, their permeability, how easy or difficult it is for fluids to flow through them.

And there are a lot of places in the world where this seismic exploration and drilling has already been done in the search for oil.

LHF: Yeah, it turns out that oil and gas tend to be found in the same kinds of malleable rocks that are good for storing CO2. Sometimes we can just turn around and use those same places for storage.

In fact, the most common way that companies store captured CO2 today is by pumping it into active oil wells to help flush more oil out. This is something called “enhanced oil recovery,” and to be clear, it’s not a long-term climate solution, because it’s used to help push out more oil that’s going to be burned and put more climate pollution into the air.

But geologists have also scouted out a lot of formations that could be used for CO2 storage without the oil production.

BH: For instance, the Gulf of Mexico is an area which is very conducive to carbon storage. But there's been a lot of extraction activity already in the Gulf, so one would have to be careful not to inject fluids near abandoned wells where the CO2 might leak back out. You know, you want to make sure that you're not in an area which had been turned into Swiss cheese by previous drilling operations.

LHF: Now, I mentioned at the beginning of this episode that carbon storage is already going on. So another question we can ask is—have we caused any leaks, or earthquakes?

BH: It depends. So there's a place in the North Sea called Sleipner, where CO2 injection has been going on for about 30 years, since the mid 1990s, at a rate of a million tons a year. And the layer that they're injecting into is so porous and so permeable, that they don't even have to pump the fluid in. It basically runs in under its own weight. It’s been a real success story.

But then there was a site in Algeria, for example, where they were injecting carbon dioxide, but the rocks were very tight. They had difficulty getting the CO2 in and there was evidence that they actually started to fracture the rock. The caprock was very thick, so the CO2 didn’t end up leaking, but they did have to halt storage.

LHF: So far, there haven’t been any CO2 storage disasters. That’s great news, and a sign that this is a plausible climate solution. But the failed project in Algeria does underscore how important it is to have responsible management of these storage sites, to monitor them and to make adjustments once they get going.

And, unfortunately, there are companies that have not always been careful enough about the environmental risks like these. For instance, we could look to something that humans pump underground today in much greater quantities than CO2: wastewater.

BH: In a lot of places where oil is produced, water is mixed in along with the oil. So the oil that's coming out is not pure. And sometimes, like in Oklahoma, they're getting 10 times as much water out as they're getting oil. So the usual way of disposing of this wastewater is to drill a hole in the ground and inject it back underground. Right now there are hundreds of billions of gallons of wastewater injected every year.

LHF: So if we’re worried about causing earthquakes when we pump carbon underground, a good first question to ask might be: are we causing earthquakes now, when we dispose of all this wastewater underground?

BH: Earthquakes can be a big problem, but they’re a tractable problem. Most wastewater is injected without causing any earthquakes at all. There are places like Saudi Arabia, for example, where a lot of wastewater is injected, and earthquakes are not resulting.

But then there are places like Oklahoma where injecting this wastewater has led to earthquakes. 

LHF: Yeah, Oklahoma saw a surge of earthquakes in the 2010s, alongside a boom in the local oil and gas industry.

BH: We knew that earthquakes were happening in Oklahoma before people began drilling for oil and gas and pumping wastewater back in. So it was known to be an area of seismic risk. And unfortunately, some companies in Oklahoma were not very careful about where they injected the wastewater.

LHF: These kinds of events are preventable, but they do have to be prevented. And that means, when there’s a proposed carbon storage project under evaluation, it’s not just the geology we have to ask questions about. We also need to ask the kinds of questions we would pose for any big infrastructure project that might impact the environment. Like, does the company have a good track record? What regulations are in place, and are they well enforced? Can we get a third party to evaluate the safety risks?

BH: It's basically a management question of carrying out the storage responsibly. And I want to be clear that there are risks. But there are risks to everything, and the risks for continuing to emit carbon dioxide into the atmosphere without taking it out far outweigh the risks of putting the CO2 underground.

LHF: That’s it for our episode today. 

Do you have a question about climate change? Maybe we answered it as part of our Ask MIT Climate series. You can find out at climate.mit.edu. And if we haven’t, ask us! Leave us a voicemail message at 617 253 3566 or visit https://climate.mit.edu/ask. We release answers as episodes here on TILclimate as well as on the website. 

I’ve got to say, we love hearing from our listeners. It totally lights up our day. We would love to hear from you, too. Let us know who you are, what you’re working on, what you’re wondering about, and why you listen to the show. Send us an email at climate@mit.edu.

TILclimate is the climate change podcast of the Massachusetts Institute of Technology. Aaron Krol is our Writer and Producer. David Lishansky is our Sound Editor and Producer. Michelle Harris is our fact-checker. Sylvia Scharf is our Climate Education Specialist. The music is by Blue Dot Sessions. And I’m your Host and Executive Producer, Laur Hesse Fisher. 

Thank you Prof. Brad Hager for speaking with us; to Barbara Ann and Christopher for your questions; to Lindsay Fendt, for original reporting used in this episode; and to you, our listeners. Keep up the curiosity.