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Is there a place in the atmosphere where carbon dioxide is concentrated, and if so, can we remove it?

Carbon dioxide mixes evenly through the atmosphere. But the atmosphere as a whole is densest near the ground, so a cubic foot of air at ground level will contain more carbon dioxide molecules than a cubic foot of air high up in the sky.

 

March 22, 2021

If the carbon dioxide (CO2) in Earth’s atmosphere were clustered in certain spots, then it might be easier to remove CO2 from the air by building machines that capture CO2 in those places. But this is not the case, says Jesse Kroll, MIT professor of civil and environmental engineering and director of the Ralph M. Parsons Laboratory for Environmental Science and Engineering. Kroll says the CO2 emitted by cars, factories, and other sources mixes thoroughly into the atmosphere, so the amount of CO2 in the air is more or less consistent around the world.

“There will be some [variations] depending on how close you are to sources or sinks,” he says. (A sink is a place where CO2 is absorbed out of the atmosphere: for example, over a forest, where trees suck in CO2 to grow.) But those variations are small, Kroll says. There is no place with especially high levels of carbon dioxide to grab. There are more CO2 molecules at the Earth’s surface compared to miles up in the sky, but that is because the atmosphere is densest down low and slowly gets thinner as you get higher.

Plucking carbon from the air

It is possible to use machines to pull CO2 out of the air. Submarines and spacecraft do this so the people inside don’t run out of oxygen to breathe. The idea of trapping CO2 from the atmosphere at large is called direct air capture (DAC), says Howard Herzog, a Senior Research Engineer in the MIT Energy Initiative and author of a recent book chapter on the subject. “DAC invokes images of machines sucking carbon dioxide out of the air, allowing the world to continue business as usual, emitting CO2 from the chimneys of our houses, the tailpipes of our cars, and the smokestacks of our industries,” Herzog writes. “No wonder DAC is such a seductive concept.”

DAC projects and plans are underway, and a few startup companies are trying to turn direct air capture into a cost-effective climate change solution. However, Herzog says, using DAC to combat climate change would require the technology to capture billions of tons of CO2 annually. That is about a million times more than what the few currently operational pilot projects can capture. The technology must become cheaper and more efficient if we are to build the big projects that would allow DAC to make a major climate impact.

Because the level of CO2 in the atmosphere is the same around the world, there is no shortcut to making direct air capture more effective. There is, however, one way to put carbon absorbers in places with extra CO2, and that’s to focus on the exhaust coming from power and industrial plants that burn fossil fuels. This kind of carbon capture is much cheaper and more efficient than DAC. But it’s also philosophically different: instead of trying to draw down the CO2 we’ve already added to the atmosphere, it aims to prevent new CO2 from entering the atmosphere.

One bright spot for DAC: it works best near the Earth’s surface—in other words, where we live—because that’s where the atmosphere is thickest, Herzog says. Direct air capture installations are made of huge, hulking machines, and if it were indeed true that most CO2 lived high in the atmosphere, then engineers might face a double challenge of building tall structures to loft CO2-absorbing materials way up in the air.

 

Thank you to William Solomon of Calderdale, West Yorkshire, U.K., for the question. You can submit your own question to Ask MIT Climate here.

 

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Want to learn more?

Listen to this episode of MIT's "Today I Learned: Climate" podcast on direct air capture and other technologies to take CO2 out of the atmosphere.

Transcriptions

LHF: [00:00:00] Hello, and welcome to Today I Learned: Climate, the show where you learn about climate change from real scientists and experts. I’m your host Laur Hesse Fisher of the MIT Environmental Solutions Initiative. We’ve had people ask us, OK, if climate change is caused by adding too much CO2 in the atmosphere, can we just suck it back out? Won’t that solve our climate change problem?

To answer this question, we spoke with someone who would know.

NM: [00:00:27] My name is Niall Mac Dowell. I'm a professor at Imperial College London, and I've been working for carbon management for about 15 years, particularly, recently, with a focus on greenhouse gas removal, or taking CO2 out of the atmosphere.

LHF: [00:00:40] Prof. Mac Dowell shared with us that this is actually pretty tricky to do at a large scale.

To understand why… well... think about the sky. Maybe you can even see it right now. That’s our atmosphere, and even though you can’t see them, there’s a whole mix of gases swirling around up there: nitrogen, oxygen, argon, water vapor … and CO2 is just one of them.

 So Prof. Mac Dowell asked us to imagine that each molecule of CO2 in the atmosphere is a red marble, and every other molecule is a blue marble.

NM: [00:01:19] So if you imagine a bucket of marbles and if we have a hundred marbles and all of the marbles are red and you're given the task of getting five red marbles. It's already easy. You just grabbed five red marbles. There's no work to do.

 If we imagine now the atmosphere, the air, it's not a hundred marbles, it's a million marbles and of this million, only about 400 of them are red, and everything else is blue. So you can spend a lot of energy, you will have to do a lot of work to search through all the blue marbles to find the red marbles. [skip] For every million tons of CO2 that you want to recover from the atmosphere, you will have to handle — you have to physically move — between 5 and 7 billion — with a B — tons of air, and a ton of air is as heavy as a ton of rock. So it's a big effort.

LHF: [00:02:10] Wow. So, is this really possible?

NM: [00:02:14] Yeah, sure. It's technically eminently feasible. As we've discussed, it requires a lot of energy, it takes a lot of work, to sort through all of the atmospheric marbles to find the carbon, but you can totally do it.

LHF: [00:02:29] And, in fact, people are doing it. Or, at least, trying it out. The technology is called “direct air capture,” because you’re capturing CO2 directly out of the air. There’s a company with three facilities in Europe, there’s a different company with one up in Canada, there’s an oil company testing it out in Texas.

NM: [00:02:50] Every time I turned around, there's news of some, somebody else, you know, proposing a DAC pilot, pilots can come in many shapes and sizes.

LHF: [00:02:59] So if I were to tour the facility, what would it look like?

NM: [00:03:03] When this has been trialed in different places — you're  talking about a bank of units, a bit like shipping containers. So say, you know, two meters by two meters, this kind of thing. And that has a big fan on it, and that fan is sucking air through and it's just sucking the air through and blowing it over some kind of contactor, which will react with the CO2 and that's directly pulling the carbon out of the atmosphere.

LHF: [00:03:28] What is the contactor? Is that a chemical solution of some kind?

NM: [00:03:33] Yeah. So very simply CO2 is an acid. So, whatever you want it to react with, will want to be some kind of base or a caustic or an alkaline material.

LHF: [00:03:44] OK so you have this, like, chemical solution that acts like a sponge, pulling out the CO2 from the air. But then, you gotta wring the sponge and get the CO2 out.

NM: [00:03:56] So you do that simply by adding energy. So if it's in the liquid form, you have to effectively boil it out. And this allows you to recover a pure string of CO2, which you can compress, transport and store.

LHF: [00:04:09] Once you have all this extracted CO2, you have to put it somewhere where it won’t go back up in the atmosphere.

NM: [00:04:17] So this is typically underground. In Texas, for example, people are talking about having direct air capture technologies to directly transport the CO2 into oil fields that are right nearby.

LHF: [00:04:29] If you want to know more about storing CO2 underground or using it to produce other things like building materials, check out our episode 7 from season 2 on carbon capture, which is about capturing the CO2 out of the smokestacks of manufacturing and power plants.

But shipping containers with big fans isn’t the only idea we have to take CO2 out of the atmosphere.

NM: [00:04:54] So. The important thing about greenhouse gas removal or carbon dioxide removal is that it's a portfolio of different approaches, some of which rely on engineered technologies — so this is direct air capture or some forms of what's known as enhanced weathering, so that's reacting CO2 with crushed rock, or bioenergy with carbon capture and storage pathways — so that could be turning biomass into heat, power, mobility, and then you capture whatever CO2 you can.

There are ways in which we can improve and change the management of our natural environment. So one good example of that, one really important example of that, is afforestation. So turning a landscape into a forest and carbon sink, and similarly changing the way in which we manage peatlands wetlands, wetland restoration.

LHF: [00:05:49] Put a pin in those last two —in our next episode, we’ll talk all about using forests to take CO2 out of the atmosphere.

Okay, let’s back up. The bottom line is that it really is possible to take CO2 out of the air. And that’s… sort of an intoxicating thought. Because if there’s one thing we’ve seen on this show, it’s that stopping our CO2 emissions [which Prof. Mac Dowell is going to call “mitigation,” “mitigating climate change”] requires us to change the way we get energy, the way we build, the way we travel, the way we grow food. So is carbon removal the easier way out of climate change?

NM: [00:06:32] In my personal opinion? No.

Greenhouse gas removal through any pathway, whether it's direct air capture, bioenergy with CCS, afforestation, or any other options, is not an alternative to mitigation.

LHF: [00:06:47] Why is that?

NM: [00:06:49] Very simply, most mitigation will be cheaper, just simply more cost-effective than greenhouse gas removal.

We are at, I think, the very early days of developing direct air capture technology. You know, the basic science is sort of there, right? We know how to capture the CO2.

The problem is that what we need to do is be actively removing lots of CO2 at the million tons per year scale minimum.

I mean, the analogy I think is that it's a bit maybe like saying we need to be able to break the sound barrier and Orville and Wilbur right now just managed to get their, you know, the first plane flying for 10 meters or whatever it was, you know, that's sort of where we are.

So it's far too early to rule anything out, but putting all your faith in the manifestation of some kind of technical unicorn, which will very, very cheaply reverse the impact of climate change, I think is brave. And I wouldn't do it.

LHF: [00:07:53] And this is the central challenge with carbon removal. If you look at it as an economist would -- how much it costs to remove or avoid a ton of CO2 --- direct air capture isn’t yet cheaper than pretty much any other option: building wind and solar, even capturing and storing CO2 from smokestacks is cheaper.

 So if it’s so expensive to take CO2 out of the atmosphere, and so much cheaper to avoid putting it there in the first place, why invest in CO2 removal at all? Well, it’s because a whole lot of CO2 has already accumulated in the atmosphere, and that CO2 is going to be warming the Earth for a long time—so we will need to remove it if we’re going to keep global warming in check.

In fact, almost every scenario scientists have come up with for how to keep global warming at relatively safe levels has large-scale carbon removal by the end of the century as one of the key tools in our toolkit.

NM: [00:08:57] We have to mitigate as fast as we can with every tool in our arsenal. And we will also very likely have to think about greenhouse gas removal options as well.

We will need everything. We need renewable energy. We need fuel switching. We need nuclear power. We need demand reduction. We need carbon capture and storage, and we will need all forms of greenhouse gas removal as and when they get going.

LHF: [00:09:24] We’re going to stay on this subject in our next episode, and talk about another way to suck out that CO2, using nature. But for now, I want to thank Prof. Mac Dowell for joining us, and remind you that you can always check out our website or Twitter @TILclimate for a bunch of resources we’ve pulled together: fun facts, other websites, our sources, and educator guides so teachers can use this podcast to introduce climate change in the classroom. As always, email us your questions at tilclimate@mit.edu, and thanks for listening.